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  6. Allylpalladium(II) chloride dimer, Pd 56.0% min, Thermo Scientific Chemicals

Allylpalladium(II) chloride dimer, Pd 56.0% min, Thermo Scientific Chemicals

Codice prodotto. 11356707
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Quantità:
0.25 g
1 g
5 g
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This item is not returnable. View return policy

Description

Allylpalladium(II) chloride dimer is used as an important catalyst in Heck reaction. It reacts with cyclopentadienyl anion to give cyclopentadienyl allyl palladium. It acts as a precatalyst for asymmetric and cross-coupling catalysis. Further, it is used in the preparation of 1,4-diallyl-1,2-dihydroisoquinolines. It is also employed as a catalyst for greener Buchwald-Hartwig coupling reaction and involved in the synthesis of cationic palladium catalysts. In addition, it takes part in preparation of -heterocyclic carbene-palladium-eta3-allyl chloride complex, which is an efficient catalyst for the Suzuki-Miyaura cross-coupling reactions in synthetic chemistry.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

TRUSTED_SUSTAINABILITY

Chemical Identifiers

CAS 12012-95-2
Formula molecolare C6H10Cl2Pd2
Molecular Weight (g/mol) 365.89
Numero MDL MFCD00044874
InChI Key PENAXHPKEVTBLF-UHFFFAOYSA-L
Sinonimo allylpalladium chloride dimer, bis allyl dichlorodipalladium, diallyldipalladium dichloride, palladium allyl chloride dimer, diallydichlorodipalladium, pi-allyl palladium chloride, allylpalladium ii chloride, bis chloro-pi-allylpalladium, allyl palladium chloride dimer, bis pi-allyl chloropalladium
PubChem CID 61538
IUPAC Name chloropalladium(1+);prop-1-ene
SMILES Cl[Pd].Cl[Pd].c:c:c.c:c:c

Specifications

Materiale o nome chimico Allylpalladium(II) chloride dimer
Punto di fusione 120°C (decomposition)
Colore Yellow
Quantità 0.25 g
Beilstein 4124623
Sensibilità Air and moisture sensitive
Informazioni di solubilità Very soluble in dichloromethane and dichloroethane; Slightly soluble in toluene,insoluble in waterSoluble in chloroform,benzene,acetone and dichloromethane,dichloroethane and methanol; Slightly soluble in toluene; Insoluble in water.
Peso formulazione 365.85
Concentration or Composition (by Analyte or Components) Pd 56.0% min.
Forma fisica Powder

Safety and Handling

compliance-icons
Product Identifier
  • di-.Mu.-chlor-bis(eta-allil)palladio
 Signal Word
  • Attenzione
 Hazard Category
  • Corrosione/irritazione della pelle Categoria 2
  • Lesione oculare grave/irritazione oculare Categoria 2
  • Tossicità specifica per organi bersaglio (esposizione singola) Categoria 3
 Hazard Statement
  • H315-Provoca irritazione cutanea.
  • H319-Provoca grave irritazione oculare.
  • H335-Può irritare le vie respiratorie.
 Precautionary Statement
  • P261-Evitare di respirare la polvere/i fumi/i gas/la nebbia/i vapori/gli aerosol.
  • P280-Indossare guanti/indumenti protettivi/Proteggere gli occhi/il viso.
  • P305+P351+P338-IN CASO DI CONTATTO CON GLI OCCHI: sciacquare accuratamente per parecchi minuti. Togliere le eventuali lenti a contatto se è agevole farlo. Continuare a sciacquare.
  • P304+P340-IN CASO DI INALAZIONE: trasportare l'infortunato all'aria aperta e mantenerlo a riposo in posizione che favorisca la respirazione.
  • P405-Conservare sotto chiave.
  • P501-Smaltire il prodotto/recipiente in .
SDS

RUO – Research Use Only

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