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1,1'-Bis(diphenylphosphino)ferrocene, 97%, Thermo Scientific Chemicals

£31.9 - £302.0

Chemical Identifiers

CAS 12150-46-8
Molecular Formula C34H28FeP2
Molecular Weight (g/mol) 554.39
MDL Number MFCD00001422
InChI Key KZPYGQFFRCFCPP-UHFFFAOYSA-N
IUPAC Name λ²-iron(2+) bis(1-(diphenylphosphanyl)cyclopenta-2,4-dien-1-ide)
SMILES [Fe].c1ccc(c1)P(C1=CC=CC=C1)C1=CC=CC=C1.c1ccc(c1)P(C1=CC=CC=C1)C1=CC=CC=C1
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Disclaimers: RUO – Research Use Only


Specification

Chemical Name or Material 1,1'-Bis(diphenylphosphino)ferrocene
CAS 12150-46-8
Melting Point ∼182°C (decomposition)
Assay Percent Range 0.97
Molecular Formula C34H28FeP2
MDL Number MFCD00001422
Quantity 5 g
Sensitivity Air sensitive
Synonym Dppf; 1,1'-Ferrocenebis(diphenylphosphine)
Solubility Information Soluble in chloroform,dichloromethane,alcohol and pentane. Insoluble in water.
InChI Key KZPYGQFFRCFCPP-UHFFFAOYSA-N
SMILES [Fe].c1ccc(c1)P(C1=CC=CC=C1)C1=CC=CC=C1.c1ccc(c1)P(C1=CC=CC=C1)C1=CC=CC=C1
IUPAC Name λ²-iron(2+) bis(1-(diphenylphosphanyl)cyclopenta-2,4-dien-1-ide)
Molecular Weight (g/mol) 554.39
Formula Weight 554.4
Percent Purity 97%

Applications
1,1′-Bis(diphenylphosphino)ferrocene acts as a ligand in homogeneous catalysis. It is used as a ligand for ruthenium-catalyzed greener amine synthesis from amines and alcohols by hydrogen-borrowing. It is also employed as a ligand for Buchwald-Hartwig cross coupling. Further, it is used in the synthesis of coordination compound as well as the formation of complexes with various metals such as palladium chloride. In addition to this, it serves as a reagent for palladium-catalyzed coupling reactions and also plays an important role in Suzuki reaction.

Solubility
Soluble in chloroform, dichloromethane, alcohol and pentane. Insoluble in water.

Notes
Air sensitive. Store in a cool place. Incompatible with strong oxidizing agents.

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11464657


Safety data sheet (SDS) 		Thermo Scientific Alfa Aesar
B21166.06
 5 g £93.0
5g
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11474657


Safety data sheet (SDS) 		Thermo Scientific Alfa Aesar
B21166.14
 25 g £302.0
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** 11454657


Safety data sheet (SDS) 		Thermo Scientific Alfa Aesar
B21166.03
 1 g n/a  
** No longer available. See item for replacement.

Product Identifier
  • 1,1'-Bis(diphenylphosphino)ferrocene

Signal Word
  • Danger

Hazard Category
  • Acute toxicity Category 3

Hazard Statement
  • H301- Toxic if swallowed.

Precautionary Statement
  • P264- Wash face, hands and anyexposed skin thoroughly after handling.
  • P270- Do not eat, drink or smoke when using this product.
  • P301+P310- IF SWALLOWED: Immediately call a POISON CENTER/doctor /
  • P330- Rinse mouth.
  • P405- Store locked up.
  • P501b- Dispose of contents/container in accordance with local/regional/national/international regulations.

Supplemental Information
  • MIXTURE LIST- Contains : 1,1'-Bis(diphenylphosphino)ferrocene